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Title: Technology development for iron Fischer-Tropsch catalysts. Technical progress report No. 4, June 26, 1991--September 26, 1991

Technical Report ·
DOI:https://doi.org/10.2172/10130666· OSTI ID:10130666

Objectives are to develop active, stable iron Fischer-Tropsch catalysts for use in slurry-phase synthesis reactors and to develop a scaleup procedure for large-scale synthesis of such catalysts for process development and long-term testing in slurry bubble-column reactors. For a H{sub 2}-CO in molar ratio of 0.5 to 1.0, catalyst performance target is 88% CO+H{sub 2} conversion at a minimum space velocity of 2.4 NL/hr/gFe, with no more than 4% methane/ethane selectivity and 1% conversion loss per week. During this period, it was found that the performance of the slurry-phase iron and copper oxide-based catalyst depends on the amount of K. Five catalysts with differing K contents were studied. The catalysts with the lowest K were more active than the ones with higher K levels. The one with the middle K level was judged best.

Research Organization:
UOP, Inc., Des Plaines, IL (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC22-90PC90055
OSTI ID:
10130666
Report Number(s):
DOE/PC/90055-T3; ON: DE92018441
Resource Relation:
Other Information: PBD: 1991
Country of Publication:
United States
Language:
English