Engineering-scale destruction of organics at Savannah River Site using the silver(II) ion
Abstract
Electrochemical destruction of organics to carbon dioxide, water, and inorganic salts using the silver(II) ion as an oxidizer has been demonstrated at the Savannah River Site (SRS) on a laboratory scale. An engineering-scale facility has been constructed at SRS for a process demonstration of the technology using benzene. Organic destruction rates, cell efficiencies and off gas generation will be related to key process variables. Electrocell design, peripheral support equipment, engineering considerations, safety issues, and operating parameters will be discussed. Future test plans and the impact of early results on the direction of the organics destruction program at SRS will also be addressed.
- Authors:
- Publication Date:
- Research Org.:
- Westinghouse Savannah River Co., Aiken, SC (United States)
- Sponsoring Org.:
- USDOE, Washington, DC (United States)
- OSTI Identifier:
- 10130127
- Report Number(s):
- WSRC-MS-91-192; CONF-911047-18
ON: DE92009776
- DOE Contract Number:
- AC09-89SR18035
- Resource Type:
- Conference
- Resource Relation:
- Conference: 180. meeting of the Electrochemical Society,Phoenix, AZ (United States),13-18 Oct 1991; Other Information: PBD: 4 Sep 1991
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; ORGANIC COMPOUNDS; OXIDATION; SILVER IONS; ELECTROCHEMICAL CELLS; DIFFUSION; BENZENE; NITRIC ACID; SAVANNAH RIVER PLANT; 400400; 052001; ELECTROCHEMISTRY; WASTE PROCESSING
Citation Formats
Fleischman, S D, and Pierce, R A. Engineering-scale destruction of organics at Savannah River Site using the silver(II) ion. United States: N. p., 1991.
Web.
Fleischman, S D, & Pierce, R A. Engineering-scale destruction of organics at Savannah River Site using the silver(II) ion. United States.
Fleischman, S D, and Pierce, R A. 1991.
"Engineering-scale destruction of organics at Savannah River Site using the silver(II) ion". United States. https://www.osti.gov/servlets/purl/10130127.
@article{osti_10130127,
title = {Engineering-scale destruction of organics at Savannah River Site using the silver(II) ion},
author = {Fleischman, S D and Pierce, R A},
abstractNote = {Electrochemical destruction of organics to carbon dioxide, water, and inorganic salts using the silver(II) ion as an oxidizer has been demonstrated at the Savannah River Site (SRS) on a laboratory scale. An engineering-scale facility has been constructed at SRS for a process demonstration of the technology using benzene. Organic destruction rates, cell efficiencies and off gas generation will be related to key process variables. Electrocell design, peripheral support equipment, engineering considerations, safety issues, and operating parameters will be discussed. Future test plans and the impact of early results on the direction of the organics destruction program at SRS will also be addressed.},
doi = {},
url = {https://www.osti.gov/biblio/10130127},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Wed Sep 04 00:00:00 EDT 1991},
month = {Wed Sep 04 00:00:00 EDT 1991}
}
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