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Title: Regenerative process for removal of mercury and other heavy metals from gases containing H.sub.2 and/or CO

Patent ·
OSTI ID:1012643

A method for removal of mercury from a gaseous stream containing the mercury, hydrogen and/or CO, and hydrogen sulfide and/or carbonyl sulfide in which a dispersed Cu-containing sorbent is contacted with the gaseous stream at a temperature in the range of about 25.degree. C. to about 300.degree. C. until the sorbent is spent. The spent sorbent is contacted with a desorbing gaseous stream at a temperature equal to or higher than the temperature at which the mercury adsorption is carried out, producing a regenerated sorbent and an exhaust gas comprising released mercury. The released mercury in the exhaust gas is captured using a high-capacity sorbent, such as sulfur-impregnated activated carbon, at a temperature less than about 100.degree. C. The regenerated sorbent may then be used to capture additional mercury from the mercury-containing gaseous stream.

Research Organization:
Gas Technology Institute (Des Plaines, IL)
Sponsoring Organization:
USDOE
DOE Contract Number:
FC26-04NT42312
Assignee:
Gas Technology Institute (Des Plaines, IL)
Patent Number(s):
7,556,672
Application Number:
11/702,237
OSTI ID:
1012643
Country of Publication:
United States
Language:
English

References (2)

Mercury Removal from Oil by Reactive Adsorption journal January 1996
Selective chemisorption and oxidation/reduction kinetics of supported copper oxide catalysts prepared from copper(II) acetylacetonate journal August 1991