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Title: Metal complex-based electron-transfer mediators in dye-sensitized solar cells

Patent ·
OSTI ID:1007908

This present invention provides a metal-ligand complex and methods for using and preparing the same. In particular, the metal-ligand complex of the present invention is of the formula: L.sub.a-M-X.sub.b where L, M, X, a, and b are those define herein. The metal-ligand complexes of the present invention are useful in a variety of applications including as electron-transfer mediators in dye-sensitized solar cells and related photoelectrochromic devices.

Research Organization:
Colorado State Univ., Fort Collins, CO (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FG03-97ER14808
Assignee:
Colorado State University Research Foundation (Fort Collins, CO); The University of Ferrara (Ferrara, IT)
Patent Number(s):
7,019,138
Application Number:
10/494,086
OSTI ID:
1007908
Country of Publication:
United States
Language:
English

References (4)

Substituted Polypyridine Complexes of Cobalt(II/III) as Efficient Electron-Transfer Mediators in Dye-Sensitized Solar Cells journal September 2002
Dual role of para-phenyl substituents in aromatic imine ligand complexes of cobalt and iron journal January 1980
Effects of silver particles on the photovoltaic properties of dye-sensitized TiO2 thin films journal April 2000
Solution Redox Couples for Electrochemical Energy Storage journal January 1982