The hydration, microstructure, and mechanical properties of vaterite calcined clay cement (VC3)
Limestone (calcite) calcined clay cement (LC3) is a promising low-CO2 binder, but the low activity of calcite cannot compensate the reduction in clinker factor, resulting in low one-day strength and limiting its broad applications. As recent carbon capture and utilization technologies allow scalable production of vaterite, a more reactive CaCO3 polymorph, we overcome the challenge by introducing vaterite calcined clay cement (VC3), inspired by the vaterite-calcite phase change. In the present study, VC3 exhibits higher compressive strengths and faster hydration than LC3. Compared to hydrated LC3, hydrated VC3 exhibits increased amount of hemi- and mono-carboaluminate formation and decreased amount ofmore »