Conversion of Nonporous Helical Cadmium Organic Famework to a Porous Form
Journal Article
·
· Chemical Communications, 46(29):5373–5375
Two novel cadmium–organic frameworks containing achiral multiwalled helical nanotubular channels, [Cd(HImDC)(S)]n (S = Im(1) and Py(2)), have been synthesized and characterized using single crystal X-ray diffraction, in which 1 converts to 2 upon refluxing 1 in pyridine solution with noticeable porosity and hydrogen uptake at medium pressure.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 984677
- Report Number(s):
- PNNL-SA-72526; ISSN 1364-548X; KC0201050; TRN: US201016%%1419
- Journal Information:
- Chemical Communications, 46(29):5373–5375, Vol. 46, Issue 29; ISSN 1359-7345
- Country of Publication:
- United States
- Language:
- English
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