Nd2K2IrO7 and Sm2K2IrO7: Iridium(VI) Oxides Prepared under Ambient Pressure
Journal Article
·
· Angewandte Chemie. International Edition in English
The most-oxidized iridium oxides known to date are prepared in a hydroxide flux under normal pressure. They contain iridium centers exclusively in the +VI oxidation state and are characterized crystallographically. The picture shows the structure of the Ln2K2IrO7 (Ln=Nd, Sm) and its structural components: IrO6 octahedra (black), KO10 polyhedra (beige), LnO10 polyhedra (blue).
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 980357
- Report Number(s):
- BNL-93275-2010-JA; TRN: US201015%%1742
- Journal Information:
- Angewandte Chemie. International Edition in English, Vol. 48; ISSN 0570-0833
- Country of Publication:
- United States
- Language:
- English
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