Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.
Abstract
Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.
- Authors:
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- EE
- OSTI Identifier:
- 973037
- Report Number(s):
- ANL/CSE/JA-65842
Journal ID: ISSN 1099-0062; TRN: US201005%%408
- Resource Type:
- Journal Article
- Journal Name:
- Electrochem. Solid State Lett.
- Additional Journal Information:
- Journal Volume: 13; Journal Issue: 4 ; 2010; Journal ID: ISSN 1099-0062
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 25 ENERGY STORAGE; BORATES; ELECTRODES; ELECTROLYTES; LITHIUM COMPOUNDS; REDOX POTENTIAL; BATTERY CHARGING; EQUIPMENT PROTECTION DEVICES; METAL-NONMETAL BATTERIES
Citation Formats
Chen, Z, Liu, J, Jansen, A N, Casteel, B, Amine, K, GirishKumar, G, and Air Products and Chemicals, Inc. Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.. United States: N. p., 2010.
Web. doi:10.1149/1.3299251.
Chen, Z, Liu, J, Jansen, A N, Casteel, B, Amine, K, GirishKumar, G, & Air Products and Chemicals, Inc. Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.. United States. https://doi.org/10.1149/1.3299251
Chen, Z, Liu, J, Jansen, A N, Casteel, B, Amine, K, GirishKumar, G, and Air Products and Chemicals, Inc. 2010.
"Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.". United States. https://doi.org/10.1149/1.3299251.
@article{osti_973037,
title = {Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.},
author = {Chen, Z and Liu, J and Jansen, A N and Casteel, B and Amine, K and GirishKumar, G and Air Products and Chemicals, Inc.},
abstractNote = {Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.},
doi = {10.1149/1.3299251},
url = {https://www.osti.gov/biblio/973037},
journal = {Electrochem. Solid State Lett.},
issn = {1099-0062},
number = 4 ; 2010,
volume = 13,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 2010},
month = {Fri Jan 01 00:00:00 EST 2010}
}
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