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Title: Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.

Abstract

Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.

Authors:
; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
EE
OSTI Identifier:
973037
Report Number(s):
ANL/CSE/JA-65842
Journal ID: ISSN 1099-0062; TRN: US201005%%408
Resource Type:
Journal Article
Journal Name:
Electrochem. Solid State Lett.
Additional Journal Information:
Journal Volume: 13; Journal Issue: 4 ; 2010; Journal ID: ISSN 1099-0062
Country of Publication:
United States
Language:
ENGLISH
Subject:
25 ENERGY STORAGE; BORATES; ELECTRODES; ELECTROLYTES; LITHIUM COMPOUNDS; REDOX POTENTIAL; BATTERY CHARGING; EQUIPMENT PROTECTION DEVICES; METAL-NONMETAL BATTERIES

Citation Formats

Chen, Z, Liu, J, Jansen, A N, Casteel, B, Amine, K, GirishKumar, G, and Air Products and Chemicals, Inc. Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.. United States: N. p., 2010. Web. doi:10.1149/1.3299251.
Chen, Z, Liu, J, Jansen, A N, Casteel, B, Amine, K, GirishKumar, G, & Air Products and Chemicals, Inc. Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.. United States. https://doi.org/10.1149/1.3299251
Chen, Z, Liu, J, Jansen, A N, Casteel, B, Amine, K, GirishKumar, G, and Air Products and Chemicals, Inc. 2010. "Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.". United States. https://doi.org/10.1149/1.3299251.
@article{osti_973037,
title = {Lithium borate cluster salts as novel redox shuttles for overcharge protection of lithium-ion cells.},
author = {Chen, Z and Liu, J and Jansen, A N and Casteel, B and Amine, K and GirishKumar, G and Air Products and Chemicals, Inc.},
abstractNote = {Redox shuttle is a promising mechanism for intrinsic overcharge protection in lithium-ion cells and batteries. Two lithium borate cluster salts are reported to function as both the main salt for a nonaqueous electrolyte and the redox shuttle for overcharge protection. Lithium borate cluster salts with a tunable redox potential are promising candidates for overcharge protection for most positive electrodes in state-of-the-art lithium-ion cells.},
doi = {10.1149/1.3299251},
url = {https://www.osti.gov/biblio/973037}, journal = {Electrochem. Solid State Lett.},
issn = {1099-0062},
number = 4 ; 2010,
volume = 13,
place = {United States},
year = {Fri Jan 01 00:00:00 EST 2010},
month = {Fri Jan 01 00:00:00 EST 2010}
}