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Title: Experimental Study of Effect of Aging and Self-healing Behavior of Glass/Ceramic Sealant on Glass/Ceramic Sealant Used in SOFC

Conference ·
OSTI ID:964236

High operating temperature of solid oxide fuel cells require that sealant must function at high temperature between 600o and 900oC and in the oxidizing and reducing environments of fuel and air. In this paper, experiment tests were implemented to investigate the effect of aging time and self-healing behavior of the glass ceramic sealant used in solid oxide fuel cells (SOFCs) on its mechanical properties. With longer heat treatment or aging time during operation, further crystallization may reduce the residual glass content while boosting the ceramic crystalline content. Meanwhile, the micro-damage was induced by the cooling down process from the operating temperature to the room temperature, which can potentially degrade the mechanical properties of the glass/ceramic sealant. During the reheat of the SOFC to the operating temperature, the glass/ceramic sealant exhibits the possible self-healing characterization, which can restore the mechanical performance of the glass/ceramic sealant.

Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-76RL01830
OSTI ID:
964236
Report Number(s):
PNNL-SA-60964; AA2530000; TRN: US200922%%154
Resource Relation:
Conference: Materials Science & Technology 2008 Conference and Exhibition: MS&T '08: October 5-9, 2008, Pittsburgh, Pennsylvania, 380-389
Country of Publication:
United States
Language:
English