Comparison of the EXAFS Spectra of Heteronuclear MnCa/Sr Model Complexes to the Oxygen-Evolving Mn(4)Ca Complex of Photosystem II
Journal Article
·
· Chem. Commun.2007:1538,2007
OSTI ID:953948
Heterometallic Mn-Ca and Mn-Sr complexes have been prepared and employed as model complexes for Ca and Sr EXAFS spectral comparisons with the Oxygen-Evolving Complex (OEC) of Photosystem II (PS II); these have revealed similarities that support the presence of at least one O atom bridge between the Mn and Ca/Sr in the OEC.
- Research Organization:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC02-76SF00515
- OSTI ID:
- 953948
- Report Number(s):
- SLAC-REPRINT-2009-444; TRN: US201004%%685
- Journal Information:
- Chem. Commun.2007:1538,2007, Vol. 2007, Issue 15; ISSN 1359-7345
- Country of Publication:
- United States
- Language:
- English
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