Pseudo-polymorphism in the toluene solvate of p-tert-butylcalix[5]arene: Structural and gas sorption investigations
Journal Article
·
· New Journal of Chemistry, 32(12):2095-2099
Crystallisation of the host molecule p-tert-butylcalix[5]arene from toluene affords three pseudo-polymorphs, two of which can be isolated on a large scale and used to form ‘frustrated’ organic solids that are capable of gas sorption. The structures of these three polymorphs are compared, as are the gas sorption capabilities of the two phases that can be isolated in bulk form
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 947900
- Report Number(s):
- PNNL-SA-57987; NJCHE5; AA2530000; TRN: US200905%%220
- Journal Information:
- New Journal of Chemistry, 32(12):2095-2099, Vol. 32, Issue 12; ISSN 1144-0546
- Country of Publication:
- United States
- Language:
- English
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