Formation of Mixed Monolayers of Silsesquioxanes and Alkylsilanes on Gold
The formation of mixed monolayers of hydridospherosilsesquioxane clusters (H{sub 8}Si{sub i}O{sub 12}) and alkylsilanes (H{sub 2n+1}C{sub n}SiH{sub 3}) on Au has been investigated using X-ray photoelectron and reflection-absorption infrared spectroscopies and scanning tunneling microscopy. All of the techniques indicate the displacement of the majority of the siloxane clusters from the surface in favor of the alkylsilane.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 930168
- Report Number(s):
- BNL-80826-2008-JA; LANGD5; TRN: US200822%%1216
- Journal Information:
- Langmuir, Vol. 22; ISSN 0743-7463
- Country of Publication:
- United States
- Language:
- English
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