Atomistic Model of Physical Ageing in Se-rich As-Se Glasses
Journal Article
·
· Philosophical Magazine B
Thermal, optical, X-ray excited and magnetic methods were used to develop a microstructural model of physical ageing in Se-rich glasses. The glass composition As10Se90, possessing a typical cross-linked chain structure, was chosen as a model object for the investigations. The effect of physical ageing in this glass was revealed by differential scanning calorimetry, whereas the corresponding changes in its atomic arrangement were studied by extended X-ray absorption fine structure, Raman and solid-state 77Se nuclear magnetic resonance spectroscopy. Straightening-shrinkage processes are shown to be responsible for the physical ageing in this Se-rich As-Se glass.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 929929
- Report Number(s):
- BNL-80523-2008-JA; TRN: US200822%%939
- Journal Information:
- Philosophical Magazine B, Vol. 87, Issue 28; ISSN 1478-6435
- Country of Publication:
- United States
- Language:
- English
Similar Records
Experimental verification of the reversibility window concept in binary As-Se glasses subjected to a long-term physical aging
Chaotic behavior of light-assisted physical aging in arsenoselenide glasses
RADIATION EFFECTS IN PHYSICAL AGING OF BINARY As-S AND As-Se GLASSES
Journal Article
·
Tue Jul 01 00:00:00 EDT 2008
· Physical Review. B, Condensed Matter and Materials Physics
·
OSTI ID:929929
+3 more
Chaotic behavior of light-assisted physical aging in arsenoselenide glasses
Journal Article
·
Mon Dec 15 00:00:00 EST 2014
· Chaos (Woodbury, N. Y.)
·
OSTI ID:929929
+3 more
RADIATION EFFECTS IN PHYSICAL AGING OF BINARY As-S AND As-Se GLASSES
Journal Article
·
Mon Jan 24 00:00:00 EST 2011
· Journal of Thermal Analysis and Calorimetry
·
OSTI ID:929929
+3 more