Launching a particle on a ring: b2u -->ke2g ionization ofC6F6
Journal Article
·
· Journal of Chemical Physics
Evidence is presented demonstrating that an electron launched into the continuum is trapped in an unprecedented quasibound state, namely, one that extends through the backbone of the six-member carbon ring of C{sub 6}F{sub 6}. The mode specificity of the vibrational sensitivity to the electron trapping provides an experimental signature for this phenomenon, while adiabatic static model-exchange scattering calculations are used to map the wave function, which corroborate the interpretation.
- Research Organization:
- COLLABORATION - Louisiana StateU.
- DOE Contract Number:
- DE-AC02-05CH11231
- OSTI ID:
- 927824
- Report Number(s):
- LBNL-61875; JCPSA6; R&D Project: 403101; BnR: KC0301020; TRN: US200816%%1076
- Journal Information:
- Journal of Chemical Physics, Vol. 125, Issue 16; Related Information: Journal Publication Date: 2006; ISSN 0021-9606
- Country of Publication:
- United States
- Language:
- English
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