Manganese Complexes of 1,3,5-triaza-7-phosphaadamantane (PTA): The First Nitrogen Bound Transition Metal Complex of PTA
The structures of two manganese(II) complexes of 1,3,5-triaza-7-phosphaadamantane (PTA) reveal the first transition-metal complexes of PTA in which the metal preferentially coordinates to a nitrogen and not the phosphorus of PTA. The coordination environment about the manganese was probed using X-ray crystallography (solid state) and EXAFS spectroscopy (solution).
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source
- Sponsoring Organization:
- Doe - Office Of Science
- DOE Contract Number:
- DE-AC02-98CH10886
- OSTI ID:
- 914094
- Report Number(s):
- BNL-78662-2007-JA; INOCAJ; TRN: US0801539
- Journal Information:
- Inorg. Chem., Vol. 45; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
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