The Effect of Palladium Additions on the Solidus/Liquidus Temperatures and Wetting Properties of Ag-CuO Based Air Brazes
Abstract
As a means of increasing the use temperature of ceramic-ceramic and ceramic-metal air brazes, palladium was investigated as possible ternary addition to the currently employed silver - copper oxide system. The silver component was directly substituted with palladium to form the following series of alloys: (100-y)[(100-z)Pd - (z)Ag] - (y)CuOx where y = 0 - 34 mol% CuOx, z = 50 - 100 mol% silver, and x = 0, 0.5, and 1, denoting copper metal, Cu2O, or CuO. From differential scanning calorimetry, it was determined that the addition of palladium causes an increase in the solidus and liquidus temperatures of the resulting Pd-Ag-CuO brazes. In general, the liquidus was found to increase by approximately 220°C for the (100-y)(25Pd - 75Ag) - (z)CuOx filler metal compositions relative to comparable Ag-CuOx alloys. Likewise, the solidus was found to increase for these alloys, respectively by 185°C and 60°C, respectively for CuOx contents of y = 0 - 1mol% and 4 - 10 mol%. For the (100-y)(50Pd - 50Ag) - (y)CuOx alloys, the solidus increased between 280 - 390°C over a copper oxide compositional range of x = 0 to 8 mol%. It was determined from sessile drop experiments conducted on alumina substrates thatmore »
- Authors:
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 909458
- Report Number(s):
- PNNL-SA-46328
Journal ID: ISSN 0925-8388; JALCEU; AA1510100; TRN: US200722%%1265
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Alloys and Compounds, 433(1-2):184-192
- Additional Journal Information:
- Journal Volume: 433; Journal Issue: 1-2; Journal ID: ISSN 0925-8388
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; ALLOYS; CALORIMETRY; COPPER; COPPER OXIDES; FILLER METALS; MICROSTRUCTURE; PALLADIUM; PALLADIUM ADDITIONS; POROSITY; SCANNING ELECTRON MICROSCOPY; SILVER; SUBSTRATES; WETTABILITY; brazing, high-temperature; metals; interfaces; scanning elecron microscopy; high-temperature alloys; thermal analysis
Citation Formats
Darsell, Jens T, and Weil, K Scott. The Effect of Palladium Additions on the Solidus/Liquidus Temperatures and Wetting Properties of Ag-CuO Based Air Brazes. United States: N. p., 2007.
Web. doi:10.1016/j.jallcom.2006.06.073.
Darsell, Jens T, & Weil, K Scott. The Effect of Palladium Additions on the Solidus/Liquidus Temperatures and Wetting Properties of Ag-CuO Based Air Brazes. United States. https://doi.org/10.1016/j.jallcom.2006.06.073
Darsell, Jens T, and Weil, K Scott. 2007.
"The Effect of Palladium Additions on the Solidus/Liquidus Temperatures and Wetting Properties of Ag-CuO Based Air Brazes". United States. https://doi.org/10.1016/j.jallcom.2006.06.073.
@article{osti_909458,
title = {The Effect of Palladium Additions on the Solidus/Liquidus Temperatures and Wetting Properties of Ag-CuO Based Air Brazes},
author = {Darsell, Jens T and Weil, K Scott},
abstractNote = {As a means of increasing the use temperature of ceramic-ceramic and ceramic-metal air brazes, palladium was investigated as possible ternary addition to the currently employed silver - copper oxide system. The silver component was directly substituted with palladium to form the following series of alloys: (100-y)[(100-z)Pd - (z)Ag] - (y)CuOx where y = 0 - 34 mol% CuOx, z = 50 - 100 mol% silver, and x = 0, 0.5, and 1, denoting copper metal, Cu2O, or CuO. From differential scanning calorimetry, it was determined that the addition of palladium causes an increase in the solidus and liquidus temperatures of the resulting Pd-Ag-CuO brazes. In general, the liquidus was found to increase by approximately 220°C for the (100-y)(25Pd - 75Ag) - (z)CuOx filler metal compositions relative to comparable Ag-CuOx alloys. Likewise, the solidus was found to increase for these alloys, respectively by 185°C and 60°C, respectively for CuOx contents of y = 0 - 1mol% and 4 - 10 mol%. For the (100-y)(50Pd - 50Ag) - (y)CuOx alloys, the solidus increased between 280 - 390°C over a copper oxide compositional range of x = 0 to 8 mol%. It was determined from sessile drop experiments conducted on alumina substrates that in all cases the palladium causes an increase in the wetting angle relative to the corresponding binary braze. Alloy compositions of (100-y)(25Pd - 75Ag) - (y)CuOx displayed increased wetting angles of 5-20° relative to comparable binary compositions. (100-y)(50Pd - 50Ag) - (y)CuOx alloys exhibited an increase in contact angle of 10-60° and compositions containing less than 10 mol% CuOx were not able to wet the substrate. Scanning electron microscopy indicated that the microstructure of the braze consists of discrete CuOx precipitates in an alloyed silver-palladium matrix. In both the binary and ternary filler metal formulations, a reaction layer consisting of CuAlO2 was observed along the interface with the alumina substrate. This reaction product appears to be beneficial in promoting wetting by the remaining braze filler metal. However the formation of this layer is hindered as the concentration of palladium in the filler metal is increased, which appears to be the primary cause of poor wettability in these compositions, as indicated by the substantial amount of porosity found along the braze/substrate interface.},
doi = {10.1016/j.jallcom.2006.06.073},
url = {https://www.osti.gov/biblio/909458},
journal = {Journal of Alloys and Compounds, 433(1-2):184-192},
issn = {0925-8388},
number = 1-2,
volume = 433,
place = {United States},
year = {Wed May 16 00:00:00 EDT 2007},
month = {Wed May 16 00:00:00 EDT 2007}
}