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Title: Project Title: Radiochemical Analysis by High Sensitivity Dual-Optic Micro X-ray Fluorescence

Abstract

A novel dual-optic micro X-ray fluorescence instrument will be developed to do radiochemical analysis of high-level radioactive wastes at DOE sites such as Savannah River Site and Hanford. This concept incorporates new X-ray optical elements such as monolithic polycapillaries and double bent crystals, which focus X-rays. The polycapillary optic can be used to focus X-rays emitted by the X-ray tube thereby increasing the X-ray flux on the sample over 1000 times. Polycapillaries will also be used to collect the X-rays from the excitation site and screen the radiation background from the radioactive species in the specimen. This dual-optic approach significantly reduces the background and increases the analyte signal thereby increasing the sensitivity of the analysis. A doubly bent crystal used as the focusing optic produces focused monochromatic X-ray excitation, which eliminates the bremsstrahlung background from the X-ray source. The coupling of the doubly bent crystal for monochromatic excitation with a polycapillary for signal collection can effectively eliminate the noise background and radiation background from the specimen. The integration of these X-ray optics increases the signal-to-noise and thereby increases the sensitivity of the analysis for low-level analytes. This work will address a key need for radiochemical analysis of high-level waste usingmore » a non-destructive, multi-element, and rapid method in a radiation environment. There is significant potential that this instrumentation could be capable of on-line analysis for process waste stream characterization at DOE sites.« less

Authors:
;
Publication Date:
Research Org.:
Los Alamos National Laboratory, Los Alamos, NM; X-Ray Optical Systems, Albany, NY (US)
Sponsoring Org.:
USDOE Office of Environmental Management (EM) (US)
OSTI Identifier:
835000
Report Number(s):
EMSP-81967-2002
R&D Project: EMSP 81967; TRN: US0407416
DOE Contract Number:  
FG07-01ER63280
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: 1 Jun 2002
Country of Publication:
United States
Language:
English
Subject:
12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; 54 ENVIRONMENTAL SCIENCES; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BREMSSTRAHLUNG; EXCITATION; FLUORESCENCE; FOCUSING; HIGH-LEVEL RADIOACTIVE WASTES; OPTICS; RADIATIONS; RADIOCHEMICAL ANALYSIS; SCREENS; SENSITIVITY; WASTES; X-RAY SOURCES; X-RAY TUBES

Citation Formats

Havrilla, George J, and Gao, Ning. Project Title: Radiochemical Analysis by High Sensitivity Dual-Optic Micro X-ray Fluorescence. United States: N. p., 2002. Web. doi:10.2172/835000.
Havrilla, George J, & Gao, Ning. Project Title: Radiochemical Analysis by High Sensitivity Dual-Optic Micro X-ray Fluorescence. United States. https://doi.org/10.2172/835000
Havrilla, George J, and Gao, Ning. 2002. "Project Title: Radiochemical Analysis by High Sensitivity Dual-Optic Micro X-ray Fluorescence". United States. https://doi.org/10.2172/835000. https://www.osti.gov/servlets/purl/835000.
@article{osti_835000,
title = {Project Title: Radiochemical Analysis by High Sensitivity Dual-Optic Micro X-ray Fluorescence},
author = {Havrilla, George J and Gao, Ning},
abstractNote = {A novel dual-optic micro X-ray fluorescence instrument will be developed to do radiochemical analysis of high-level radioactive wastes at DOE sites such as Savannah River Site and Hanford. This concept incorporates new X-ray optical elements such as monolithic polycapillaries and double bent crystals, which focus X-rays. The polycapillary optic can be used to focus X-rays emitted by the X-ray tube thereby increasing the X-ray flux on the sample over 1000 times. Polycapillaries will also be used to collect the X-rays from the excitation site and screen the radiation background from the radioactive species in the specimen. This dual-optic approach significantly reduces the background and increases the analyte signal thereby increasing the sensitivity of the analysis. A doubly bent crystal used as the focusing optic produces focused monochromatic X-ray excitation, which eliminates the bremsstrahlung background from the X-ray source. The coupling of the doubly bent crystal for monochromatic excitation with a polycapillary for signal collection can effectively eliminate the noise background and radiation background from the specimen. The integration of these X-ray optics increases the signal-to-noise and thereby increases the sensitivity of the analysis for low-level analytes. This work will address a key need for radiochemical analysis of high-level waste using a non-destructive, multi-element, and rapid method in a radiation environment. There is significant potential that this instrumentation could be capable of on-line analysis for process waste stream characterization at DOE sites.},
doi = {10.2172/835000},
url = {https://www.osti.gov/biblio/835000}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Sat Jun 01 00:00:00 EDT 2002},
month = {Sat Jun 01 00:00:00 EDT 2002}
}