Interaction of uranyl molybdate with the Na{sub 2}MoO{sub 4}-Na{sub 2}Mo{sub 2}O{sub 4} melt
Journal Article
·
· Russian Journal of Electrochemistry
OSTI ID:75644
- Institute of High Temperature Electrochemistry, Ekaterinburg (Russian Federation)
Behavior of uranyl molybdate in molten Na{sub 2}MoO{sub 4}-Na{sub 2}Mo{sub 2}O{sub 7} salt mixture at 1073 K in air was studied using cyclic linear voltammetry and potentiometric titration techniques. Uranyl complexes of two types ([UO{sub 2}(MoO{sub 4}){sub 2}]{sup 2{minus}} and UO{sub 3}MoO{sub 4}{sup 2{minus}}) were shown to be formed in the solution upon the addition of UO{sub 2}MoO{sub 4}. The composition of a cathodic product was found to be determined by the molar ratio of these two complexes in the melt.
- OSTI ID:
- 75644
- Journal Information:
- Russian Journal of Electrochemistry, Vol. 30, Issue 6; Other Information: PBD: Jun 1994; TN: Translated from Elektrokhimiya; 30: No. 6, 781-784(1994)
- Country of Publication:
- United States
- Language:
- English
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