Methylation of the phosphoryl group by methyl iodide

Journal Article · Fri Jan 10 00:00:00 EST 1986 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7252093

Koidan, G N; Marchenko, A P; Pinchuk, A M

The authors have established that hexaalkyltriamidophosphazo groups are unusually strong electron-donor substituents at P /SUP III/ , causing the extremely high basicity of such compounds. This paper performs methylation of tris (tris (N,N-dimethylamido) phosphazo) phosphate and tris (tris (N,N-dimethylamido) phosphazo) methoxyphosphonium iodide (I) using methyl oxide. The NMR spectra were recorded on a Bruker WP-20 spectrometer, and hexamethyldisiloxane and 85% H/sub 3/PO/sub 4/ were used as the standard.

• Research Organization: Institute of Organic Chemistry, Ukrainian SSR Acad. of Sci., Kiev
• OSTI ID: 7252093
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 55:7,PT. 2
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
METHYL IODIDE
CATALYTIC EFFECTS
ORGANIC PHOSPHORUS COMPOUNDS
METHYLATION
BINDING ENERGY
NMR SPECTRA
PHOSPHATES
PHOSPHORIC ACID
PHOSPHORUS 31
SILOXANES
VALENCE
CHEMICAL REACTIONS
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
IODINATED ALIPHATIC HYDROCARBONS
ISOTOPES
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC SILICON COMPOUNDS
OXYGEN COMPOUNDS
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
SPECTRA
STABLE ISOTOPES
400201* - Chemical & Physicochemical Properties