Mechanism of the oxo reaction. I The conversion of cobalt carbonyls during the oxo reaction. The promoting effect of organic bases

Journal Article · Wed Jan 01 00:00:00 EST 1986 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:7251991

Borovikov, M S; Rybakov, V A

The authors use the Breslow-Heck mechanism to examine the conversions of cobalt carbonyls during the oxo reaction. An interrelationship was found between hydrogen activation (catalysis of the hydrogenolysts of Co/sub 2/(CO)/sub 8/) and olefin activation (acceleration of the oxo reaction). A mechanism was proposed for the promoting effect of organic bases in the oxo reaction.

• Research Organization: All-Union Petrochemical Processes Research Institute, Leningrad
• OSTI ID: 7251991
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 26:4,PT.1
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKENES
CARBONYLATION
CARBONYLS
CATALYTIC EFFECTS
COBALT COMPOUNDS
CATALYSTS
CHEMICAL ACTIVATION
COORDINATION VALENCES
HYDROGEN
PROMOTERS
CHEMICAL REACTIONS
ELEMENTS
HYDROCARBONS
NONMETALS
ORGANIC COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
VALENCE
400201* - Chemical & Physicochemical Properties