Inhibition of the polymerization of methyl methacrylate and methyl acrylate by mixtures of chloranil with phenothiazine

Journal Article · Sun Sep 01 00:00:00 EDT 1985 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:7251813

Ivanov, A A; Lysenko, G M; Zholina, I N

This paper investigates the kinetic peculiarities of inhibited polymerization of methyl methacrylate and methyl acrylate in the presence of mixtures of chloranil with phenothiazine. It is shown that depending on the structure of the monomer and the concentrations of the electron donor and electron acceptor, the radicals of propagation may form complexes with chloranil or with phenothiazine at the first step of the inhibition reaction or may interact with the complex (phenothiazine to chloranil).

• Research Organization: N.V. Lomonosov Moscow Institute of Fine Chemical Technology
• OSTI ID: 7251813
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 26:2,PT.1
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
METHACRYLIC ACID ESTERS
COPOLYMERIZATION
METHYL METHACRYLATE
PMMA
CHEMICAL REACTION YIELD
INHIBITION
BINDING ENERGY
CHEMICAL REACTION KINETICS
CHLORANIL
COMPLEXOMETRY
ELECTRONS
MOLECULAR STRUCTURE
PHENOTHIAZINES
REDOX REACTIONS
VALENCE
AROMATICS
AZINES
BENZOQUINONES
CARBOXYLIC ACID ESTERS
CHEMICAL REACTIONS
ELEMENTARY PARTICLES
ENERGY
ESTERS
FERMIONS
HETEROCYCLIC COMPOUNDS
KINETICS
LEPTONS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC POLYMERS
ORGANIC SULFUR COMPOUNDS
POLYACRYLATES
POLYMERIZATION
POLYMERS
POLYVINYLS
QUINONES
REACTION KINETICS
YIELDS
400201* - Chemical & Physicochemical Properties