Reactions of organometallic compounds, catalyzed by transition metal complexes. 8. Carbonylation of arylmercury compounds in the presence of palladium and rhodium

Journal Article · Mon May 20 00:00:00 EDT 1985 · Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)

OSTI ID:7222513

Bumagin, N A; Beletskaya, I P; Kalinovskii, I O

The authors show that in the presence of iodide ion the carbonylation of arylmercury compounds R/sub 2/Hg and RHgX, catalyzed by palladium and rhodium complexes, proceeds under very mild conditions to give high yields of symmetrical diaryl ketones. The effects of type of solvent and catalyst, and the type and amount of halide ion have been examined, and the optimum conditions for carbonylation have been found.

• Research Organization: M.V. Lomonosov Moscow State Univ.
• OSTI ID: 7222513
• Journal Information: Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Vol. 33:11, PT. 2
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
IODINE COMPOUNDS
CATALYTIC EFFECTS
KETONES
CHEMICAL REACTION YIELD
ORGANIC MERCURY COMPOUNDS
CARBONYLATION
HETEROGENEOUS CATALYSIS
PALLADIUM COMPLEXES
RHODIUM COMPLEXES
CATALYSTS
CHEMICAL REACTION KINETICS
OPTIMIZATION
CATALYSIS
CHEMICAL REACTIONS
COMPLEXES
HALOGEN COMPOUNDS
KINETICS
MERCURY COMPOUNDS
ORGANIC COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENT COMPLEXES
YIELDS
400201* - Chemical & Physicochemical Properties