Linear free energy relationships in glass corrosion

Conference · Fri Jan 01 00:00:00 EST 1988

OSTI ID:7179346

Abrajano, Jr, T A; Bates, J K; Bohlke, J K

Various theoretical models that have been proposed to correlate glass durability to their composition for a wide variety of silicate, borosilicate, and aluminosilicate glasses are examined. Comparisons are made between the predictions of these models and those of an empirical formulation extracted from existing data in the present work. The empirical approach provides independent confirmation of the relative accuracy of the silica release rate predictions of the different theoretical models in static leaching systems. Extension of the empirical approach used in this work are discussed. 23 refs., 2 figs., 1 tab.

• Research Organization: Argonne National Lab., IL (USA)
• DOE Contract Number: W-31109-ENG-38
• OSTI ID: 7179346
• Report Number(s): CONF-8804134-2; ON: DE88012050; TRN: 88-027649
• Resource Relation: Conference: Symposium on materials stability and environmental degradation, Reno, NV, USA, 5 Apr 1988; Other Information: Portions of this document are illegible in microfiche products
• Country of Publication: United States
• Language: English

Related Subjects

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS
36 MATERIALS SCIENCE
EXPERIMENTAL DATA
COMPARATIVE EVALUATIONS
GLASS
CORROSION
MATHEMATICAL MODELS
CHEMICAL REACTION KINETICS
EXTRAPOLATION
GROUND DISPOSAL
HIGH-LEVEL RADIOACTIVE WASTES
LEACHING
CHEMICAL REACTIONS
DATA
DISSOLUTION
INFORMATION
KINETICS
MANAGEMENT
MATERIALS
NUMERICAL DATA
NUMERICAL SOLUTION
RADIOACTIVE MATERIALS
RADIOACTIVE WASTES
REACTION KINETICS
SEPARATION PROCESSES
WASTE DISPOSAL
WASTE MANAGEMENT
WASTES
052002* - Nuclear Fuels- Waste Disposal & Storage
053000 - Nuclear Fuels- Environmental Aspects
360603 - Materials- Properties