Effects of polar aprotic solvents on the rate of the topochemical reaction of benzoyl chloride with sodium azide in o-xylene

Journal Article · Tue Oct 01 00:00:00 EDT 1985 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:7150832

Zlobin, V A

The kinetics of the topochemical reaction of benozyl chloride with sodium azide in o-xylene have been examined in the presence of varying amounts of acetonitrile and dimethylformamide. The specific rates and activation energies for the reaction have been found. These parameters have been found to increase with the amounts of polar aprotic solvent added. The observed dependence is explained by a change in the mechanism of the reaction.

• Research Organization: V.V. Kuibyshev Polytechnic Institute
• OSTI ID: 7150832
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 26:2,PT.2
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AZIDES
HETEROGENEOUS CATALYSIS
ORGANIC CHLORINE COMPOUNDS
CATALYTIC EFFECTS
ACETONITRILE
ACTIVATION ENERGY
CHEMICAL REACTION KINETICS
FORMAMIDE
ORGANIC SOLVENTS
SODIUM COMPOUNDS
SOLVENT PROPERTIES
XYLENES
ALKALI METAL COMPOUNDS
ALKYLATED AROMATICS
AMIDES
AROMATICS
CATALYSIS
ENERGY
HYDROCARBONS
KINETICS
NITRILES
NITROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
REACTION KINETICS
SOLVENTS
400201* - Chemical & Physicochemical Properties