Macrokinetic characteristics of isobutylene polymerization

Journal Article · Fri Aug 01 00:00:00 EDT 1986 · Dokl. Phys. Chem. (Engl. Transl.); (United States)

OSTI ID:7032496

Minsker, K S; Berlin, A A; Enikolopyan, N S; Prochukhan, Y A; Svinkov, A G

This paper describes a method of obtaining oligo and polyisobutylene with a molecular mass of 112-50,000: the cationic polymerization of isobutylene carried out in the presence of AlCl/sub 3/, in an environment of hydrocarbons (butanes, etc.) or chlorinated hydrocarbons (ethyl chloride, methyl chloride, etc.) at a temperature of 173-353 K/sub 3/ and in mixer-reactors of complicated design with a volume of 1.5-30 m.

• Research Organization: Bashkir State Univ, Ufa
• OSTI ID: 7032496
• Journal Information: Dokl. Phys. Chem. (Engl. Transl.); (United States), Vol. 286:4-6
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
2-METHYLPROPENE
POLYMERIZATION
ALUMINIUM CHLORIDES
CATALYTIC EFFECTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL REACTORS
HYDROCARBONS
ORGANIC POLYMERS
THERMODYNAMICS
ALKENES
ALUMINIUM COMPOUNDS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
KINETICS
ORGANIC COMPOUNDS
POLYMERS
REACTION KINETICS
YIELDS
400201* - Chemical & Physicochemical Properties