Structure and reactivity of chemisorbed species and reaction intermediates: Progress report, December 1, 1985-November 30, 1986
The areas of work supported under this contract by DOE during the period 12/1/85-11/30/86 have a common theme: the structure and reactivity of chemisorbed species and reaction intermediates of importance to catalysis. A variety of tools have been used to study the structure and chemistry of surface species, and to develop models and concepts of broad utility in chemisorption and catalysis. Fourteen papers have appeared, are in press, or in preparation in FY86. Results of the research conducted or completed in the last year are summarized in this report. The results are presented in three sections: surface molecular structure and reactivity as studied using electron stimulated desoprtion ion angular distribution (ESDIAD) and high resolution electron energy loss spectroscopy (HREELS); neutron inelastic scattering studies of adsorption and reaction on metal catalysts and zeolite catalysts; reaction kinetics at high pressures over single crystal metal catalysts: mechanisms of catalyst poisoning. A listing of publications during the past year is included.
- Research Organization:
- National Bureau of Standards, Washington, DC (USA). Surface Science Div.
- DOE Contract Number:
- AT01-77ER72027
- OSTI ID:
- 7006171
- Report Number(s):
- DOE/ER/72027-T1; ON: DE87002998
- Country of Publication:
- United States
- Language:
- English
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Structure and reactivity of chemisorbed species and reaction intermediates: Progress report, 1 December 1987--30 November 1988
Structure and reactivity of chemisorbed species and reaction intermediates. Summary of results FY 82
Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON MONOXIDE
ADSORPTION
CHROMIUM
SORPTIVE PROPERTIES
IRON
OXYGEN
CHEMISORPTION
RUTHENIUM
WATER
ANGULAR DISTRIBUTION
CATALYSIS
ENERGY-LOSS SPECTROSCOPY
HYDROGEN
MOLECULAR STRUCTURE
PALLADIUM
SURFACES
TUNGSTEN
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DISTRIBUTION
ELECTRON SPECTROSCOPY
ELEMENTS
HYDROGEN COMPOUNDS
METALS
NONMETALS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
SEPARATION PROCESSES
SORPTION
SPECTROSCOPY
SURFACE PROPERTIES
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties
400102 - Chemical & Spectral Procedures