Reactions of adducts of phosphorus pentachloride and oxa-containing nucleophiles with arsenic trifluoride

Journal Article · Sun Dec 20 00:00:00 EST 1987 · J. Gen. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:7005357

Fridland, S V; Miftakhov, M N; Arkhipov, V P

Results are given on the synthesis of phosphonofluoridates by the reactions of arsenic trifluoride with adducts of phosphorus pentachloride with oxa-containing nucleophiles. The nucleophiles used were saturated ethers, dioxolanes, and vinyl ethers. Reaction products were identified by means of NMR spectroscopy using H 1, P 31, and C 13. A full analysis of chemical shift and spin-spin coupling constant behavior as well as the spectral structure is conducted.

• Research Organization: S. M. Kirov Kazan' Institute of Chemical Technology (USSR)
• OSTI ID: 7005357
• Journal Information: J. Gen. Chem. USSR (Engl. Transl.); (United States), Vol. 57:7; Other Information: Translated from Zh. Obshch. Khim.; 57: No. 7, 1518-1526(Jul 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
74 ATOMIC AND MOLECULAR PHYSICS
ORGANIC FLUORINE COMPOUNDS
NMR SPECTRA
SYNTHESIS
ORGANIC PHOSPHORUS COMPOUNDS
ACTIVATION ENERGY
ADDUCTS
ARSENIC FLUORIDES
CARBON 13
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
CHEMICAL SHIFT
COUPLING CONSTANTS
DIENES
ETHERS
HYDROGEN 1
J-J COUPLING
PHOSPHORUS 31
PHOSPHORUS CHLORIDES
STRUCTURAL CHEMICAL ANALYSIS
ARSENIC COMPOUNDS
CARBON ISOTOPES
CHLORIDES
CHLORINE COMPOUNDS
COUPLING
ENERGY
EVEN-ODD NUCLEI
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
HYDROGEN ISOTOPES
INTERMEDIATE COUPLING
ISOTOPES
KINETICS
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
PHOSPHORUS COMPOUNDS
PHOSPHORUS ISOTOPES
POLYENES
REACTION KINETICS
SPECTRA
STABLE ISOTOPES
YIELDS
400201* - Chemical & Physicochemical Properties
640302 - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory