Rate constant measurement of the recombination reaction C[sub 3]H[sub 3] + C[sub 3]H[sub 3]

Journal Article · Thu Jul 14 00:00:00 EDT 1994 · Journal of Physical Chemistry; (United States)

DOI:https://doi.org/10.1021/j100079a023· OSTI ID:6980697

Morter, C L; Farhat, S K; Adamson, J D; Glass, G P; Curl, R F ^[1]

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1. Rice Univ., Houston, TX (United States)

Using the technique of infrared kinetic absorption spectroscopy, the second-order rate constant for the recombination reaction of the propargyl radical (C[sub 3]H[sub 3] + C[sub 3]H[sub 3]) has been measured and found to have the value (1.2 [+-] 0.2) x 10[sup [minus]10] cm[sup 3] molecule[sup [minus]1] s[sup [minus]1] at 295 K. The radical was produced in a flow cell by excimer laser flash photolysis ([lambda] = 193 nm) of the precursors C[sub 3]H[sub 3]Cl or C[sub 3]H[sub 3]Br and detected using time-resolved IR absorption. Absolute concentrations of C[sub 3]H[sub 3] were determined by comparing the C[sub 3]H[sub 3] absorption intensity with that of the Br atom. This calibration scheme was checked by producing methyl radicals by photolysis of methyl bromide and comparing the rate constant for methyl recombination thus obtained with literature values. The quantum yield for HCl production from the photodissociation of C[sub 3]H[sub 3]Cl at 193 nm was determined to be 0.07 [+-] 0.01. 47 refs., 10 figs., 1 tab.

• OSTI ID: 6980697
• Journal Information: Journal of Physical Chemistry; (United States), Vol. 98:28; ISSN 0022-3654
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BROMINATED ALIPHATIC HYDROCARBONS
PHOTOLYSIS
CHLORINATED ALIPHATIC HYDROCARBONS
RADICALS
RECOMBINATION
REACTION KINETICS
ABSORPTION SPECTROSCOPY
CALIBRATION
CARBON DIOXIDE
EXCIMER LASERS
HYDROBROMIC ACID
HYDROCHLORIC ACID
INFRARED SPECTRA
METHYL BROMIDE
METHYL RADICALS
ALKYL RADICALS
BROMINE COMPOUNDS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
CHLORINE COMPOUNDS
DECOMPOSITION
GAS LASERS
HALOGEN COMPOUNDS
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
KINETICS
LASERS
ORGANIC BROMINE COMPOUNDS
ORGANIC CHLORINE COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PHOTOCHEMICAL REACTIONS
SPECTRA
SPECTROSCOPY
400201* - Chemical & Physicochemical Properties
400102 - Chemical & Spectral Procedures
400500 - Photochemistry