Decomposition of peracetic acid catalyzed by vanadium complexes
Abstract
This paper studies the decomposition of peracetic acid (AcOOH) in acetic acid (AcOH) catalyzed by vanadium complexes. It is shown that peractic acid in acetic acid solutions of ammonium anadate decomposes with the predominant formation of 0/sub 2/ and small amounts of CO/sub 2/, the yield of which increases with increasing temperature and peracetic acid concentration. Both reactions proceed without the formation of free radicals in amounts detectable by ESR spectroscopy. The rate of oxygen release under conditions in which the formation of CO/sub 2/ is insignificant obeys a kinetic equation indicating the intermediate formation of a complex between V/sup 5 +/ ions and peracetic acid and the slow conversion of this complex into the observed products.
- Authors:
- Publication Date:
- Research Org.:
- N.S. Kurnakov Institute of General Chemistry, Moscow
- OSTI Identifier:
- 6968336
- Resource Type:
- Journal Article
- Journal Name:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
- Additional Journal Information:
- Journal Volume: 34:8,PT. 2
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; DECOMPOSITION; CHEMICAL REACTION KINETICS; VANADIUM COMPLEXES; CATALYTIC EFFECTS; ACETIC ACID; AMMONIUM COMPOUNDS; CARBON DIOXIDE; CHEMICAL REACTION YIELD; ELECTRON SPIN RESONANCE; EMISSION SPECTRA; GAS PRODUCTION RATES; OXYGEN; SOLUTIONS; SPECTROSCOPY; CARBON COMPOUNDS; CARBON OXIDES; CARBOXYLIC ACIDS; CHALCOGENIDES; CHEMICAL REACTIONS; COMPLEXES; DISPERSIONS; ELEMENTS; KINETICS; MAGNETIC RESONANCE; MIXTURES; MONOCARBOXYLIC ACIDS; NONMETALS; ORGANIC ACIDS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; REACTION KINETICS; RESONANCE; SPECTRA; TRANSITION ELEMENT COMPLEXES; YIELDS; 400201* - Chemical & Physicochemical Properties
Citation Formats
Makarov, A P, Gekhman, A E, Moiseev, I I, and Polotryuk, O Y. Decomposition of peracetic acid catalyzed by vanadium complexes. United States: N. p., 1986.
Web.
Makarov, A P, Gekhman, A E, Moiseev, I I, & Polotryuk, O Y. Decomposition of peracetic acid catalyzed by vanadium complexes. United States.
Makarov, A P, Gekhman, A E, Moiseev, I I, and Polotryuk, O Y. 1986.
"Decomposition of peracetic acid catalyzed by vanadium complexes". United States.
@article{osti_6968336,
title = {Decomposition of peracetic acid catalyzed by vanadium complexes},
author = {Makarov, A P and Gekhman, A E and Moiseev, I I and Polotryuk, O Y},
abstractNote = {This paper studies the decomposition of peracetic acid (AcOOH) in acetic acid (AcOH) catalyzed by vanadium complexes. It is shown that peractic acid in acetic acid solutions of ammonium anadate decomposes with the predominant formation of 0/sub 2/ and small amounts of CO/sub 2/, the yield of which increases with increasing temperature and peracetic acid concentration. Both reactions proceed without the formation of free radicals in amounts detectable by ESR spectroscopy. The rate of oxygen release under conditions in which the formation of CO/sub 2/ is insignificant obeys a kinetic equation indicating the intermediate formation of a complex between V/sup 5 +/ ions and peracetic acid and the slow conversion of this complex into the observed products.},
doi = {},
url = {https://www.osti.gov/biblio/6968336},
journal = {Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)},
number = ,
volume = 34:8,PT. 2,
place = {United States},
year = {Sat Feb 01 00:00:00 EST 1986},
month = {Sat Feb 01 00:00:00 EST 1986}
}