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Title: Application of chemical methods to assess the mechanism of alkali activation in low calcium fly ash

Conference ·
OSTI ID:696743
; ;  [1]
  1. Pennsylvania State Univ., PA (United States). Materials Research Lab.

A better understanding of the amount of fly ash unreacted remaining after alkali activation of low calcium fly ash is necessary for elucidating the underlying alkali activation mechanism. An approach to this determination is reported in this study which utilizes an ethylenediamine tetraacetic acid/triethanolamine/NaOH mixture to determine the unreacted fly ash particles present in an OPC-low calcium fly ash mixture, with and without alkali activation. This study also uses another chemical technique called orthophosphoric acid dissolution method to assess the amount of unreacted crystalline phases present in hydrated OPC-ash mixtures at different ages of hydration. The information obtained from these two chemical techniques was used to identify the nature of unreacted fly ash particles present in the hydrated samples. The amount of unreacted fly ash and the compressive strength data were correlated to assess the extent of influence of alkali activation on the reactivity of the amorphous and crystalline phase content of the low calcium fly ash.

Research Organization:
Illinois Inst. of Tech., Chicago, IL (United States)
OSTI ID:
696743
Report Number(s):
CONF-990410-PROC.-Vol.2; TRN: IM9946%%128
Resource Relation:
Conference: 61. American power conference annual meeting, Chicago, IL (United States), 6-8 Apr 1999; Other Information: PBD: 1999; Related Information: Is Part Of Proceedings of the American power conference: Volume 61-2; McBride, A.E. [ed.]; PB: 485 p.
Country of Publication:
United States
Language:
English