Photo- and thermochromic spirans. 16. * 2-oxo-3-phenyl-5,5-dimethylspiro(1,3-oxazolidine-4,2'-(2H) chromenes)

Journal Article · Sat Feb 01 00:00:00 EST 1986 · Chem. Heterocycl. Compd. (Engl. Transl.); (United States)

OSTI ID:6962010

Luk'yanov, B S; Chernysh, Y E; Minkin, V I; Nivorozhkin, L E

New spirans of the 5,5-dimethyl-3-phenyl-2-oxazolidone series that display photochromic properties in alcohol solutions at about-80/sup 0/C were synthesized. The photoinduced forms are characterized by the presence of two long-wave absorption bands at 350-420 nm and 500-650 nm. The /sup 1/H and /sup 13/C NMR spectra were studied. Anisochronicity of the diastereotopic methyl groups of the oxazolidone ring shows up respectively. only in the /sup 13/C NMR spectra.

• Research Organization: A.M. Suslov Rostov Univ., Rostov-on-Don
• OSTI ID: 6962010
• Journal Information: Chem. Heterocycl. Compd. (Engl. Transl.); (United States), Vol. 21:8
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBON 13
CHEMICAL SHIFT
HYDROGEN 1
OXAZOLES
NMR SPECTRA
SYNTHESIS
PHOTOCHROMIC MATERIALS
BENZENE
CHEMICAL REACTION KINETICS
ETHANOL
IRRADIATION
TEMPERATURE EFFECTS
ALCOHOLS
AROMATICS
AZOLES
CARBON ISOTOPES
EVEN-ODD NUCLEI
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROGEN ISOTOPES
HYDROXY COMPOUNDS
ISOTOPES
KINETICS
LIGHT NUCLEI
MATERIALS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
REACTION KINETICS
SPECTRA
STABLE ISOTOPES
400500* - Photochemistry