Trace element-sulfide mineral association in eastern oil shale
Eastern oil shales including the Chattanooga Shale in Tennessee and the various other time-equivalent black shales in the central portion of the United States represent a major source of hydrocarbons. A primary concern for the development of eastern oil shale and all fossil fuels is the high concentration of sulfide minerals and associated with these materials. The objectives of this study were (1) to evaluate trace elements in sulfide minerals from a Chattanooga Shale core from central Tennessee and (2) establish mineral residence and stratigraphic distribution of selected trace elements. Previous researchers have suggested the residency of the trace elements As, Cu, Cd, Pb, Mo, Ni, and Zn as being sulfide minerals, either as separate distinct phases, inclusions, or isomorphous substitution. The most significant contribution derived from the present study is the direct observation and association of selected trace and minor elements with sulfide minerals. Rather than an indirect or inferred trace element- sulfide mineral association, sulfide mineral phases were isolated allowing the morphology and composition to be directly evaluated. 9 refs., 31 figs., 3 tabs.
- Research Organization:
- Western Research Inst., Laramie, WY (United States)
- Sponsoring Organization:
- DOE/FE
- DOE Contract Number:
- FC21-86MC11076
- OSTI ID:
- 6928054
- Report Number(s):
- DOE/MC/11076-2831; ON: DE90000497
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
OIL SHALES
SULFUR CONTENT
ARSENIC SULFIDES
GALENA
MARCASITE
MINERALS
PYRITE
SCANNING ELECTRON MICROSCOPY
SPHALERITE
TENNESSEE
TRACE AMOUNTS
X-RAY DIFFRACTION
ARSENIC COMPOUNDS
BITUMINOUS MATERIALS
CARBONACEOUS MATERIALS
CHALCOGENIDES
COHERENT SCATTERING
DIFFRACTION
ELECTRON MICROSCOPY
ENERGY SOURCES
FEDERAL REGION IV
FOSSIL FUELS
FUELS
IRON COMPOUNDS
IRON SULFIDES
LEAD COMPOUNDS
LEAD SULFIDES
MATERIALS
MICROSCOPY
NORTH AMERICA
SCATTERING
SULFIDE MINERALS
SULFIDES
SULFUR COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
USA
040500* - Oil Shales & Tar Sands- Properties & Composition