Palladium-catalyzed oxidative carbonylation of ethylene and propylene by butyl nitrite and carbon monoxide
- Institut Francais du Petrole, Rueil-Malmaison (France)
In the oxidative carbonylation of ethylene by carbon monoxide and butyl nitrite catalyzed by PdCl{sub 2}(PhCN){sub 2} in the presence of triphenylphosphine, the pentacoordinated tetravalent palladium complex PdCl{sub 2}(COOBu)NO(PPh{sub 3}) has been isolated and has proved to be an intermediate in the catalytic cycle.
- OSTI ID:
- 6880999
- Journal Information:
- Organometallics; (USA), Vol. 9:1; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ETHYLENE
CARBONYLATION
PROPYLENE
CARBON MONOXIDE
CATALYSIS
DATA ANALYSIS
EXPERIMENTAL DATA
NITRITES
PALLADIUM
ALKENES
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DATA
ELEMENTS
HYDROCARBONS
INFORMATION
METALS
NITROGEN COMPOUNDS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
TRANSITION ELEMENTS
400200* - Inorganic
Organic
& Physical Chemistry
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ETHYLENE
CARBONYLATION
PROPYLENE
CARBON MONOXIDE
CATALYSIS
DATA ANALYSIS
EXPERIMENTAL DATA
NITRITES
PALLADIUM
ALKENES
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
CHEMICAL REACTIONS
DATA
ELEMENTS
HYDROCARBONS
INFORMATION
METALS
NITROGEN COMPOUNDS
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PLATINUM METALS
TRANSITION ELEMENTS
400200* - Inorganic
Organic
& Physical Chemistry