Kinetics of the. gamma. -radiation-initiated reaction of 2-propanol with tri- and hexafluoropropylene

Journal Article · Mon Feb 01 00:00:00 EST 1988 · Kinet. Catal. (Engl. Transl.); (United States)

OSTI ID:6869441

Zamyslov, R A; Shostenko, A G; Dobrov, I V; Tarasova, N P

The initiation of telomerization reactions by ionizing radiation provides good opportunities for studying the kinetics of free radical reactions. The fluoroalcohols and their derivatives prepared using fluoroolefins and aliphatic alcohols find wide practical application. The object of this exercise was to study the reactivity of trifluoropropylene and hexafluoropropylene with 2-propanol. The reaction products were analyzed gas chromatographically.

• Research Organization: D. I. Mendeleev Moscow Chemical Engineering Institute (USSR)
• OSTI ID: 6869441
• Journal Information: Kinet. Catal. (Engl. Transl.); (United States), Vol. 28:4; Other Information: Translated from Kinet. Katal; 28: No. 4, 977-979(Jul-Aug 1988)
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
FLUORINATED ALIPHATIC HYDROCARBONS
CHEMICAL RADIATION EFFECTS
TELOMERIZATION
PROPANOLS
ACTIVATION ENERGY
CHEMICAL REACTION KINETICS
GAMMA RADIATION
GAS CHROMATOGRAPHY
IRRADIATION
PROPYLENE
RADICALS
TEMPERATURE DEPENDENCE
ALCOHOLS
ALKENES
CHEMICAL REACTIONS
CHEMISTRY
CHROMATOGRAPHY
ELECTROMAGNETIC RADIATION
ENERGY
HALOGENATED ALIPHATIC HYDROCARBONS
HYDROCARBONS
HYDROXY COMPOUNDS
IONIZING RADIATIONS
KINETICS
ORGANIC COMPOUNDS
ORGANIC FLUORINE COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
POLYMERIZATION
RADIATION CHEMISTRY
RADIATION EFFECTS
RADIATIONS
REACTION KINETICS
SEPARATION PROCESSES
400600* - Radiation Chemistry