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Title: Models of ionospheric release experiments. Part 1: SF[sub 6] releases; Part 2: CO[sub 2] releases. Scientific report No. 1

Technical Report ·
OSTI ID:6848614

High-altitude chemical releases are investigated with the use of several numerical models of chemistry, dynamics, and electrodynamics. The specific releases investigated were SF[sub 6] and CO[sub 2] in the F-region of the ionosphere. The chemistry for reproducing observations from the CRRES-at-Kwajalein SF[sub 6] release must include oxidation reactions of ions and neutrals. The dominant negative ion observed, F(-), was modeled well with SF(-)[sub 5] + O yields SOF[sub 4] + F(-) as the dominant production mechanism. SOF(-)[sub 3] is potentially an important negative ion resulting from electron attachment of SOF[sub 4]. The electrodynamic model of the SF[sub 6] release did not produce a plasma depletion plume as was hoped. The electrodynamic perturbation is small and short-lived. It will not produce large-scale plume structure associated with equatorial spread-F. The modeling of CO[sub 2] releases produced too much 6300A airglow when compared with REDAIR experimental results. The conflict between simulation and experiment requires reduction of CO[sub 2] + O(+) reaction rates or inclusion of a CO[sub 2] removal mechanism such as freezing. Modeling also shows that the two CO[sub 2] releases of the REDAIR experiment may have spatially mixed airglow signatures.

Research Organization:
Mission Research Corp., Nashua, NH (United States)
OSTI ID:
6848614
Report Number(s):
AD-A-257764/1/XAB; CNN: F19628-90-C-0118
Country of Publication:
United States
Language:
English