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Title: Absolute isotopic abundance ratio and atomic weight of a reference sample of gallium

Technical Report ·
OSTI ID:6836936

An absolute value was obtained for the isotopic abundance ratio of a reference sample of gallium (Standard Reference Material 994), using thermal-ionization mass spectrometry. Samples of known isotopic composition, prepared from nearly isotopically pure separated gallium isotopes, were used to calibrate the mass spectrometers. The resulting absolute (69)Ga/(71)/Ga ratio is 1.50676 + or - 0.00039, which yields atom percents of (69)Ga=60.1079 + or - 0.0062 and (71)Ga=39.8921 + or - 0.0062. The atomic weight calculated from this isotopic composition is 69.72307 + or - 0.00013. The indicated uncertainties are overall limits of error based on two standard deviations of the mean and allowances for the effects of known sources of possible systematic error.

Research Organization:
National Bureau of Standards, Washington, DC (USA). Center for Analytical Chemistry
OSTI ID:
6836936
Report Number(s):
PB-87-137170/XAB; TRN: 87-009319
Resource Relation:
Other Information: Included in J. of Research of the National Bureau of Standards, Vol. 91, No. 6, 323-331(Nov-Dec 1986)
Country of Publication:
United States
Language:
English