A new ortho-metalated dichloro-bridged complex of iridium(III) with 2,2 prime -bipyridine: ((Ir(bpy-C sup 3 ,N prime )(bpy-N,N prime )Cl) sub 2 )(Cl) sub 2
Journal Article
·
· Inorganic Chemistry; (USA)
- Univ. of California, Santa Barbara (USA)
A novel orthomethalated dichloro-bridged dimer of the composition ((Ir(bpy-C{sup 3},N{prime}) (bpy-N,N{prime})Cl){sub 2}){sup 2+} was produced by the reaction of iridium chlorides with 2,2{prime}-bipyridine under controlled conditions. Results of elemental, molecular weight, mass spectroscopic, and {sup 1}H and {sup 13}C NMR spectral analyses are consistent with the proposed structure. The cyclic voltametric studies showed to reversible oxidation waves indicative of a dinuclear species, and acid-base character noted for the iridium complex is consistent with a species possessing a basic nitrogen site, and this is consistent with the proposed structure. 6 refs., 1 fig.
- DOE Contract Number:
- FG03-88ER13842
- OSTI ID:
- 6835212
- Journal Information:
- Inorganic Chemistry; (USA), Vol. 29:4; ISSN 0020-1669
- Country of Publication:
- United States
- Language:
- English
Similar Records
Synthesis and characterization of technetium(III) complexes containing 2,2 prime -bipyridine and 1,10-phenanthroline. X-ray crystal structures of cis (Cl),trans(P)-(TcCl sub 2 (P(CH sub 3 ) sub 2 C sub 6 H sub 5 ) sub 2 (bpy))B(C sub 6 H sub 5 ) sub 4 , cis (Cl),trans(P)-(TcCl sub 2 (P(CH sub 3 ) sub 2 C sub 6 H sub 5 ) sub 2 (phen))B(C sub 6 H sub 5 ) sub 4 , and cis (Cl),trans(P)-(TcCl sub 2 (P(CH sub 3 CH sub 2 )(C sub 6 H sub 5 ) sub 2 ) sub 2 (bpy))SO sub 3 CF sub 3
Photoinitiated electron collection in a mixed-metal trimetallic complex of the form [[(bpy)[sub 2]Ru(dpb)][sub 2]IrCl[sub 2]](PF[sub 6])[sub 5] (bpy = 2,2[prime]-bipyridine and dpb = 2,3-Bis(2-pyridyl)benzoquinoxaline)
Electrochemistry in liquid SO[sub 2]. 12. Electrochemical and pulse radiolysis studies on oxidation of Zn(bpy)[sub 3][sup 2+], Cd(bpy)[sub 3][sup 2+], and 2,2[prime]-bipyridine
Journal Article
·
Wed May 03 00:00:00 EDT 1989
· Inorganic Chemistry; (USA)
·
OSTI ID:6835212
Photoinitiated electron collection in a mixed-metal trimetallic complex of the form [[(bpy)[sub 2]Ru(dpb)][sub 2]IrCl[sub 2]](PF[sub 6])[sub 5] (bpy = 2,2[prime]-bipyridine and dpb = 2,3-Bis(2-pyridyl)benzoquinoxaline)
Journal Article
·
Wed Jun 15 00:00:00 EDT 1994
· Journal of the American Chemical Society; (United States)
·
OSTI ID:6835212
+1 more
Electrochemistry in liquid SO[sub 2]. 12. Electrochemical and pulse radiolysis studies on oxidation of Zn(bpy)[sub 3][sup 2+], Cd(bpy)[sub 3][sup 2+], and 2,2[prime]-bipyridine
Journal Article
·
Wed Aug 04 00:00:00 EDT 1993
· Inorganic Chemistry; (United States)
·
OSTI ID:6835212
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
STRUCTURAL CHEMICAL ANALYSIS
CHLORINE COMPLEXES
IRIDIUM COMPLEXES
ORGANOMETALLIC COMPOUNDS
CARBON 13
NMR SPECTRA
PROTONS
AZINES
BARYONS
CARBON ISOTOPES
COMPLEXES
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUCLEONS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
STRUCTURAL CHEMICAL ANALYSIS
CHLORINE COMPLEXES
IRIDIUM COMPLEXES
ORGANOMETALLIC COMPOUNDS
CARBON 13
NMR SPECTRA
PROTONS
AZINES
BARYONS
CARBON ISOTOPES
COMPLEXES
ELEMENTARY PARTICLES
EVEN-ODD NUCLEI
FERMIONS
HADRONS
HETEROCYCLIC COMPOUNDS
ISOTOPES
LIGHT NUCLEI
NUCLEI
NUCLEONS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PYRIDINES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation