Major kinetic features of the formation of the. pi. -complex of cobalt hydrocarbonyl with olefin and its conversion to R'Co(CO)/sub 4/
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6812284
The major kinetic features were studied for the formation of the ..pi..-complex of cobalt hydrocarbonyl with 1-hexene and its conversion to R'Co(CO)/sub 4/. The composition of the catalytically active ..pi..-complex with the olefin was established. The slow steps of the hydroformylation reaction were determined. A procedure was proposed for the preparation of solutions of cobalt hydrocarbonyl containing a ..pi..-complex with an olefin or R'Co(CO)/sub 4/.
- Research Organization:
- S.M. Kirov Ural Polytechnic Institute
- OSTI ID:
- 6812284
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Vol. 27:2
- Country of Publication:
- United States
- Language:
- English
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OSTI ID:6812284
+3 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
CATALYTIC EFFECTS
SYNTHESIS
COBALT CARBONATES
COBALT COMPLEXES
CARBONYLATION
CATALYSIS
CHEMICAL REACTION KINETICS
HEPTANE
HEXENES
KINETIC EQUATIONS
MEDIUM PRESSURE
MEDIUM TEMPERATURE
PYRIDINES
QUANTITY RATIO
SULFURIC ACID
TEMPERATURE EFFECTS
ALKANES
ALKENES
AZINES
CARBON COMPOUNDS
CARBONATES
CHEMICAL REACTIONS
COBALT COMPOUNDS
COMPLEXES
EQUATIONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
KINETICS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBONYLS
CATALYTIC EFFECTS
SYNTHESIS
COBALT CARBONATES
COBALT COMPLEXES
CARBONYLATION
CATALYSIS
CHEMICAL REACTION KINETICS
HEPTANE
HEXENES
KINETIC EQUATIONS
MEDIUM PRESSURE
MEDIUM TEMPERATURE
PYRIDINES
QUANTITY RATIO
SULFURIC ACID
TEMPERATURE EFFECTS
ALKANES
ALKENES
AZINES
CARBON COMPOUNDS
CARBONATES
CHEMICAL REACTIONS
COBALT COMPOUNDS
COMPLEXES
EQUATIONS
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
HYDROGEN COMPOUNDS
INORGANIC ACIDS
KINETICS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
REACTION KINETICS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties