Structural charge and cesium retention in a chronosequence of tephritic soils
- Pennsylvania State Univ., University Park, PA (United States). Dept. of Agronomy
- Univ. of California, Santa Barbara, CA (United States). Dept. of Geography
Mineral transformation during the course of soil development is probably coupled to time-dependent trends in surface-charge and selective adsorption behavior, but the relationships are not well documented. The density of permanent (structural) charge is subject to change as a result of accretion or depletion of 2:1 layer-type silicates. The objectives of this study were to measure changes in (i) Cs{sup +} selectivity and (ii) structural charge as affected by pedogenic mineral transformations in an age sequence of Hawaiian soils. The Cs{sup +} {r_arrow} Li{sup +} exchange experiments were conducted on soils collected from six sites [basaltic parent material deposited 0.3, 20, 150, 400, 1400 and 4100 thousands of years (ky) ago]. Identical exchange experiments were performed with kaolinite, montmorillonite, and illite for comparison. Selectivity for Cs{sup +} on soils and clays increased with adsorbed mole fraction of Cs{sup +}. Cesium-accessible structural charge of the surface soils increased initially with soil age from 20 mmol{sub c} kg{sup {minus}1} at the 0.3 ky site to 113 mmol{sub c} kg{sup {minus}1} at the 400-ky site. Increased weathering beyond 400 ky reduced structural charge to 21 mmol{sub c} kg{sup {minus}1} for the oldest site. Parallel results were observed for subsurface soils with maximum structural charge of 138 mmol{sub c} kg{sup {minus}1} measured for the 400 ky site. The magnitude of Cs retention in the soils is correlated with the presence of 2:1 layer-type silicates detected by x-ray diffraction (XRD) after removal of poorly crystalline constituents. The results indicate a modest accumulation of secondary 2:1 layer-type silicates (with larger accumulations of poorly crystalline clays), followed by their subsequent decline, during the course of soil weathering.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 679472
- Journal Information:
- Soil Science Society of America Journal, Vol. 63, Issue 1; Other Information: PBD: Jan-Feb 1999
- Country of Publication:
- United States
- Language:
- English
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