Dipping of terms in atomic calculations
Journal Article
·
· Opt. Spectrosc. (Engl. Transl.); (United States)
OSTI ID:6761625
The paper discusses the orthogonality conditions for calculations in the single-configuration approximation of the autoionization states 1s2s/sup 2/ and 2s/sup 2/ in Li and He/sup -/ and He and He/sup -/, respectively. The necessity is demonstrated of considering the conditions of orthogonality of the complete wave functions of these configurations to the wave functions of the corresponding continuous spectrum in the calculation of energy by means of the variational method.
- OSTI ID:
- 6761625
- Journal Information:
- Opt. Spectrosc. (Engl. Transl.); (United States), Vol. 55:5
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
74 ATOMIC AND MOLECULAR PHYSICS
HELIUM
AUTOIONIZATION
HELIUM IONS
LITHIUM
VARIATIONAL METHODS
WAVE FUNCTIONS
ALKALI METALS
CHARGED PARTICLES
ELEMENTS
FLUIDS
FUNCTIONS
GASES
IONIZATION
IONS
METALS
NONMETALS
RARE GASES
640302* - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory
HELIUM
AUTOIONIZATION
HELIUM IONS
LITHIUM
VARIATIONAL METHODS
WAVE FUNCTIONS
ALKALI METALS
CHARGED PARTICLES
ELEMENTS
FLUIDS
FUNCTIONS
GASES
IONIZATION
IONS
METALS
NONMETALS
RARE GASES
640302* - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory