Synthesis and Characterization of palladium crystallites intercalated in montmorillonite
Journal Article
·
· Chemistry of Materials; (United States)
- Koninklijke/Shell-Lab., Amsterdam (Netherlands)
Reduction of electrophilic Pd(II) complexes intercalated in montmorillonite under mild conditions (0[degrees]C in MeOH) has been shown to afford highly despersed metallic palladium, located mainly in the interlamellar regions of the clay. Transmission electron microscopy reveals an unusual platelet morphology for the interlammellar metal particles, suggesting that the clay structure may impose a kinetic constraint on the attainment of a thermodynamically more favorable spherical morphology. 15 refs., 3 figs., 2 tabs.
- OSTI ID:
- 6717130
- Journal Information:
- Chemistry of Materials; (United States), Vol. 5:1; ISSN 0897-4756
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
02 PETROLEUM
PALLADIUM COMPOUNDS
CHEMICAL PREPARATION
CLATHRATES
MONTMORILLONITE
PALLADIUM
REDUCTION
TRANSMISSION ELECTRON MICROSCOPY
CHEMICAL REACTIONS
CLAYS
ELECTRON MICROSCOPY
ELEMENTS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
METALS
MICROSCOPY
PLATINUM METALS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties
020400 - Petroleum- Processing
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
02 PETROLEUM
PALLADIUM COMPOUNDS
CHEMICAL PREPARATION
CLATHRATES
MONTMORILLONITE
PALLADIUM
REDUCTION
TRANSMISSION ELECTRON MICROSCOPY
CHEMICAL REACTIONS
CLAYS
ELECTRON MICROSCOPY
ELEMENTS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
MATERIALS
METALS
MICROSCOPY
PLATINUM METALS
SYNTHESIS
TRANSITION ELEMENT COMPOUNDS
TRANSITION ELEMENTS
400201* - Chemical & Physicochemical Properties
020400 - Petroleum- Processing