Detection of hydrazine compounds in gaseous samples by their conversion to nitric oxide-yielding derivatives
This patent describes a method of detecting the presence of hydrazine, monomethylhydrazine, and unsymmetrical dimethylhydrazine in a gaseous sample, essentially in real time. The method consists of the steps of: (a) contacting a gaseous sample with aldehyde or ketone vapors to convert hydrazine, monomethylhydrazine, and unsymmetrical dimethylhydrazine in the sample to hydrazine derivatives; (b) heating the sample in the presence of an oxidant to decompose derivatives produced in steps (a) to produce nitric oxide gas; and (c) determining the amount of nitric oxide gas produced in step (b), wherein any nitric oxide gas determined is indicative of the presence of hydrazine, monomethylhydrazine, and unsymmetrical dimethylhydrazine in the gaseous sample.
- Assignee:
- Thermedics Inc., Woburn, MA
- Patent Number(s):
- US 4775633
- OSTI ID:
- 6668229
- Resource Relation:
- Patent File Date: Filed date 5 Jan 1987
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
GASEOUS WASTES
AIR POLLUTION MONITORING
GASES
DERIVATIZATION
HYDRAZINE
DETECTION
ALDEHYDES
DECOMPOSITION
GASIFICATION
HEATING
KETONES
METHYL RADICALS
NITRIC OXIDE
VAPORS
ALKYL RADICALS
CHALCOGENIDES
CHEMICAL REACTIONS
FLUIDS
NITROGEN COMPOUNDS
NITROGEN OXIDES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RADICALS
THERMOCHEMICAL PROCESSES
WASTES
400201* - Chemical & Physicochemical Properties