High methane formation during the temperature-programmed decomposition in flowing hydrogen of supported mononuclear and polynuclear carbonyl complexes
Journal Article
·
· J. Am. Chem. Soc.; (United States)
This paper presents the first detailed study of the temperature-programmed decomposition (TPDE) in flowing hydrogen of every element which forms a stable carbonyl. The investigation shows that these systems have an unexpectedly high propensity to form methane. The parameters affecting the yield of methane are described and this stoichiometric reaction is compared to catalytic methanation. (AT)
- Research Organization:
- Wayne State Univ., Detroit, MI
- OSTI ID:
- 6612216
- Journal Information:
- J. Am. Chem. Soc.; (United States), Vol. 103:1
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CHROMIUM COMPLEXES
CATALYTIC EFFECTS
DECOMPOSITION
COBALT COMPLEXES
IRIDIUM COMPLEXES
IRON COMPLEXES
MANGANESE COMPLEXES
METHANATION
MOLYBDENUM COMPLEXES
NICKEL COMPLEXES
OSMIUM COMPLEXES
RHENIUM COMPLEXES
RHODIUM COMPLEXES
TUNGSTEN COMPLEXES
VANADIUM COMPLEXES
ALUMINIUM OXIDES
CARBONYLS
CATALYST SUPPORTS
HYDROGEN
METHANE
ALKANES
ALUMINIUM COMPOUNDS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
ELEMENTS
HYDROCARBONS
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
TRANSITION ELEMENT COMPLEXES
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CHROMIUM COMPLEXES
CATALYTIC EFFECTS
DECOMPOSITION
COBALT COMPLEXES
IRIDIUM COMPLEXES
IRON COMPLEXES
MANGANESE COMPLEXES
METHANATION
MOLYBDENUM COMPLEXES
NICKEL COMPLEXES
OSMIUM COMPLEXES
RHENIUM COMPLEXES
RHODIUM COMPLEXES
TUNGSTEN COMPLEXES
VANADIUM COMPLEXES
ALUMINIUM OXIDES
CARBONYLS
CATALYST SUPPORTS
HYDROGEN
METHANE
ALKANES
ALUMINIUM COMPOUNDS
CHALCOGENIDES
CHEMICAL REACTIONS
COMPLEXES
ELEMENTS
HYDROCARBONS
NONMETALS
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
TRANSITION ELEMENT COMPLEXES
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties