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Title: On the road to HF mitigation

Journal Article · · Hydrocarbon Processing; (USA)
OSTI ID:6607255
;  [1]
  1. Exxon Research and Engineering Co., Florham Park, NJ (USA)

The hazards of hydrogen fluoride (HF) have long been recognized and industry performance reflects sound operating practices. However, full-scale industry-sponsored HF release test conducted at the U.S. Department of Energy (DOE) test site in 1986 caused concern in view of HF's toxicity. Ambient impacts were greater than anticipated. And diking, a primary mitigation technique, proved ineffective for releases of pressurized superheated HF. In partial response to these new technical data, an ad-hoc three-component Industry Cooperative Hydrogen Fluoride Mitigation Assessment Program (ICHMAP) was begun in late 1987 to study and test techniques for mitigating accidental releases of HF and alkylation unit acid (AUA) and to enhance capabilities to estimate ambient impacts from such releases. AUA is a mixture of HF and hydrocarbons. The program's mitigation components have recently been completed while work on the impact assessment component is nearing completion. This article describes the program and summarizes the objective, scope of work, structure, and conclusions from the program's two mitigation components. In addition, the objectives and scope of work of the impact assessment components are described.

OSTI ID:
6607255
Journal Information:
Hydrocarbon Processing; (USA), Vol. 69:6; ISSN 0018-8190
Country of Publication:
United States
Language:
English