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Title: Nuclear magnetic resonance studies of molten salts. Progress report 1 January-31 December 1983

Abstract

This report describes work in the areas of the measurement and interpretation of 13C NMR chemical shifts of room temperature molten salts of various composition formed from aluminum chloride and 1-methyl-3-ethylimidazolium chloride; the measurement and interpretation of 25Al NMR lineshapes as a function of temperature and melt composition; the NMR study of the reaction of acidic AlCl3/1-methyl-3-ethylimidazolium molten salt with dissolved chlorine; and the redistribution of halide on aluminum during the mixing of acidic chloride and bromide melts in acetonitrile solvent. As part of the study of the effect of temperature on the 27Al NMR lineshapes of the molten salts, a computer program is given which uses a matrix method to simulate NMR lineshapes as a function of chemical shifts and exchange rates.

Authors:
; ; ;
Publication Date:
Research Org.:
Air Force Academy, CO (USA). Frank J. Seiler Research Lab.
OSTI Identifier:
6492181
Report Number(s):
AD-A-141751/8; FJSRL-TR-83-0006
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ALUMINIUM BROMIDES; NMR SPECTRA; ALUMINIUM CHLORIDES; ALUMINIUM COMPLEXES; ACETONITRILE; ALUMINIUM 27; BROMIDES; CARBON; CARBON 13; CHEMICAL COMPOSITION; CHEMICAL PROPERTIES; CHEMICAL SHIFT; CHLORIDES; COMPUTERIZED SIMULATION; IMIDAZOLES; MIXING; MOLTEN SALTS; NUCLEAR MAGNETIC RESONANCE; REACTION KINETICS; SHAPE; SOLVENTS; ALUMINIUM COMPOUNDS; ALUMINIUM ISOTOPES; AZOLES; BROMINE COMPOUNDS; CARBON ISOTOPES; CHLORINE COMPOUNDS; COMPLEXES; ELEMENTS; EVEN-ODD NUCLEI; HALIDES; HALOGEN COMPOUNDS; HETEROCYCLIC COMPOUNDS; ISOTOPES; KINETICS; LIGHT NUCLEI; MAGNETIC RESONANCE; NITRILES; NONMETALS; NUCLEI; ODD-EVEN NUCLEI; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; RESONANCE; SALTS; SIMULATION; SPECTRA; STABLE ISOTOPES; 400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987); 400201 - Chemical & Physicochemical Properties

Citation Formats

Reynolds, G F, Wilkes, J S, Levisky, J A, and Fannin, Jr, A A. Nuclear magnetic resonance studies of molten salts. Progress report 1 January-31 December 1983. United States: N. p., 1983. Web.
Reynolds, G F, Wilkes, J S, Levisky, J A, & Fannin, Jr, A A. Nuclear magnetic resonance studies of molten salts. Progress report 1 January-31 December 1983. United States.
Reynolds, G F, Wilkes, J S, Levisky, J A, and Fannin, Jr, A A. 1983. "Nuclear magnetic resonance studies of molten salts. Progress report 1 January-31 December 1983". United States.
@article{osti_6492181,
title = {Nuclear magnetic resonance studies of molten salts. Progress report 1 January-31 December 1983},
author = {Reynolds, G F and Wilkes, J S and Levisky, J A and Fannin, Jr, A A},
abstractNote = {This report describes work in the areas of the measurement and interpretation of 13C NMR chemical shifts of room temperature molten salts of various composition formed from aluminum chloride and 1-methyl-3-ethylimidazolium chloride; the measurement and interpretation of 25Al NMR lineshapes as a function of temperature and melt composition; the NMR study of the reaction of acidic AlCl3/1-methyl-3-ethylimidazolium molten salt with dissolved chlorine; and the redistribution of halide on aluminum during the mixing of acidic chloride and bromide melts in acetonitrile solvent. As part of the study of the effect of temperature on the 27Al NMR lineshapes of the molten salts, a computer program is given which uses a matrix method to simulate NMR lineshapes as a function of chemical shifts and exchange rates.},
doi = {},
url = {https://www.osti.gov/biblio/6492181}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Dec 01 00:00:00 EST 1983},
month = {Thu Dec 01 00:00:00 EST 1983}
}

Technical Report:
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