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Title: Low energy crossed beam study of the reaction H/sup +//sub 2/+Ne. -->. HNe/sup +/+H

Journal Article · · J. Chem. Phys.; (United States)
OSTI ID:6456548

We present a study of the title reaction over the relative translational energy range 0.87 to 4.05 eV. At all collision energies the products are formed with translational energy significantly in excess of the predictions of the spectator stripping model. Experiments performed with differing values of the reagent mean vibrational energy suggest that the high lying vibrational states of H/sup +//sub 2/ preferentially yield highly internally excited HNe/sup +/ products. We discuss the role of a gradual approach to the potential surface barrier as a mechanism for yielding highly translationally excited HNe/sup +/ products.

Research Organization:
Department of Chemistry, University of Rochester, Rochester, New York 14627
OSTI ID:
6456548
Journal Information:
J. Chem. Phys.; (United States), Vol. 75:4
Country of Publication:
United States
Language:
English