Telomerization of isoprene with phthalimide at complex palladium catalysts

Journal Article · Sun Jan 10 00:00:00 EST 1988 · J. Org. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6420676

Zakharkin, M I; Guseva, V V; Sulaimankulova, D D; Petrushkina, E A

The telomerization of isoprene with phthalimide takes place smoothly at complex palladium catalysts with the formation of a mixture of N-dimethyloctadienyl-phthalimides, which give a mixture of seven dimethyloctadienylamines when treated with hydrazine. By comparison of the samples of all the mixtures of N-dimethyloctadienyldimethylamines by GLC we established that terpene amines are formed during the telomerization of isoprene with phthalimide followed by cleavage of the mixture of telomers with hydrazine hydrate.

• OSTI ID: 6420676
• Journal Information: J. Org. Chem. USSR (Engl. Transl.); (United States), Vol. 23:8; Other Information: Translated from Zh. Org. Khim.; 23: No. 8, 1654-1656(Aug 1987)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ISOPRENE
TELOMERIZATION
PALLADIUM COMPLEXES
CATALYTIC EFFECTS
AMIDES
AMINES
CATALYSTS
CHROMATOGRAPHY
HYDRAZINE
IMIDES
POTASSIUM COMPOUNDS
STRUCTURAL CHEMICAL ANALYSIS
ALKALI METAL COMPOUNDS
CHEMICAL REACTIONS
COMPLEXES
DIENES
HYDROCARBONS
NITROGEN COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
POLYENES
POLYMERIZATION
SEPARATION PROCESSES
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties