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Title: Synthesis of 1-alkylthio-3-allylthio-1-propenes by the reaction of dialllyl disulfide with allyl halides in the alkali-metal hydroxide-DMSO superbasic system

Synthesis of 1-alkylthio-3-allylthio-1-propenes by the reaction of dialllyl disulfide with allyl halides in the alkali-metal hydroxide-DMSO superbasic system The reaction of diallyl disulfide with alkyl halides in the alkali-metal hydroxide-DMSO superbasic system leads to the formation of 1-alkylthio-3-allylthio-1-propenes and 1,3-di(alkylthio)propenes. The effects of the structure of the alkyl halides, the nature of the alkali-metal cations, the halogen, and the reaction conditions on the yield and ratio of the products were investigated.
Authors: ; ; ; ; ;
Publication Date:
OSTI Identifier:OSTI ID: 6388212
Resource Type:Journal Article
Resource Relation:Journal Name: J. Org. Chem. USSR (Engl. Transl.); (United States); Journal Volume: 22:5; Other Information: Translated from Zh. Org. Khim.; 22: No.5, 957-964(May 1986)
Research Org:Irkutsk Institute of Organic Chemistry, USSR
Country of Publication:United States
Language:English
Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 74 ATOMIC AND MOLECULAR PHYSICS; ALKENES; NMR SPECTRA; SYNTHESIS; BROMINATED ALIPHATIC HYDROCARBONS; ACTIVATION ENERGY; CHLORINATED ALIPHATIC HYDROCARBONS; DISULFIDES; IODINATED ALIPHATIC HYDROCARBONS; CARBON 13; CATALYTIC EFFECTS; CHEMICAL REACTION KINETICS; CHEMICAL REACTION YIELD; CHEMICAL SHIFT; COMPARATIVE EVALUATIONS; COUPLING CONSTANTS; DEUTERIUM COMPOUNDS; DMSO; HYPERFINE STRUCTURE; IONIZATION; ISOMERIZATION; ISOMERS; J-J COUPLING; LITHIUM HYDROXIDES; MASS SPECTRA; METHYL IODIDE; POTASSIUM HYDROXIDES; SODIUM HYDROXIDES; SOLVENT PROPERTIES; STRUCTURAL CHEMICAL ANALYSIS; ALKALI METAL COMPOUNDS; CARBON ISOTOPES; CHEMICAL REACTIONS; COUPLING; ENERGY; EVEN-ODD NUCLEI; HALOGENATED ALIPHATIC HYDROCARBONS; HYDROCARBONS; HYDROGEN COMPOUNDS; HYDROXIDES; INTERMEDIATE COUPLING; ISOTOPES; KINETICS; LIGHT NUCLEI; LITHIUM COMPOUNDS; NUCLEI; ORGANIC BROMINE COMPOUNDS; ORGANIC CHLORINE COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC HALOGEN COMPOUNDS; ORGANIC IODINE COMPOUNDS; ORGANIC SULFUR COMPOUNDS; OXYGEN COMPOUNDS; POTASSIUM COMPOUNDS; REACTION KINETICS; SODIUM COMPOUNDS; SPECTRA; STABLE ISOTOPES; SULFOXIDES; YIELDS 400201* -- Chemical & Physicochemical Properties; 640302 -- Atomic, Molecular & Chemical Physics-- Atomic & Molecular Properties & Theory