Aldehyde insertion into a platinum hydride and subsequent nucleophilic attack of the alkoxide at phosphorus: Platinum-alkoxide/phosphorus-aryl metathesis
- Shell Research BV, Amsterdam (Netherlands)
- Univ. of Bristol (England)
Pt(Ph{sub 2}PO)(Ph{sub 2}POH){sub 2}H (1) was treated with o-(diphenylphosphino)benzaldehyde to give a cyclic platinum alkoxide (2). The latter rearranges to the new product 3 (Scheme I), containing 1-phenyl-3H-2,1-benzoxaphosphole and a phenyl group coordinated to platinum, via a nucleophilic attack at the coordinated phosphorus center by the alkoxy group, followed by a shift of a phenyl group from phosphorus to platinum. The crystal structure of 3 has been determined.
- OSTI ID:
- 6379573
- Journal Information:
- Organometallics; (USA), Vol. 9:8; ISSN 0276-7333
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PLATINUM HYDRIDES
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
ORGANOMETALLIC COMPOUNDS
DATA
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
PLATINUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
PLATINUM HYDRIDES
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
ORGANOMETALLIC COMPOUNDS
DATA
HYDRIDES
HYDROGEN COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
PLATINUM COMPOUNDS
TRANSITION ELEMENT COMPOUNDS
400201* - Chemical & Physicochemical Properties