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Title: The electrical performance of polymeric insulating materials under accelerated aging in a fog chamber

Journal Article · · IEEE Trans. Power Del.; (United States)
DOI:https://doi.org/10.1109/61.193898· OSTI ID:6372185
; ;  [1];  [2]
  1. Univ. of Windsor, Windsor, Ontario (CA)
  2. Dow Corning Corp., Midland, MI (US)

A comparative study of the ac (60 Hz) surface aging in a fog chamber is reported on cylindrical rod samples of high temperature vulcanized (HTV) silicone rubber and ethylene propylene diene monomer (EPDM) rubber containing various amounts of alumina trihydrate (ATH) and/or silica fillers. In low conductivity (250 ..mu..S/cm) fog, silicone rubber performed better than EPDM samples whereas in high conductivity (1000 ..mu..S/cm) fog, the order of performance was reversed. The mechanisms by which fillers impart tracking and erosion resistance to materials is discussed as influenced by the experimental conditions of the accelerated aging tests. Surface studies by ESCA (Electron Spectroscopy for Chemical Analysis) demonstrate that the hydrophobicity of silicone rubber, despite the accumulation of surface contamination, can be attributed to migration of low molecular weight polymer chains and/or mobile fluids, such as silicone oil.

OSTI ID:
6372185
Journal Information:
IEEE Trans. Power Del.; (United States), Vol. 3:3
Country of Publication:
United States
Language:
English